A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds
نویسندگان
چکیده
منابع مشابه
A two-dimensional hydrogen bonded organic framework self-assembled from a three-fold symmetric carbamate.
A flexible organic sheet spontaneously assembled under mild conditions from a tri-carbamate. By introducing cyclohexyl side chains as 'pillars' between the sheets, a hydrogen bonded organic framework was formed which displayed a capacity for accommodating and releasing guest molecules. The guest size/shape selectivity of the lamellar framework was demonstrated by testing with various guests.
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Molecules of 2-nitrobenzaldehyde hydrazone, C7H7N3O2, where Z' = 2, are linked by two N-H...N hydrogen bonds into isolated dimers, whereas in the isomeric 3-nitrobenzaldehyde hydrazone, where Z' = 1, the molecules are linked by one N-H...O hydrogen bond and one N-H...N hydrogen bond into a three-dimensional framework structure.
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Ordered porous solid-state architectures constructed via non-covalent supramolecular self-assembly have attracted increasing interest due to their unique advantages and potential applications. Porous metal-coordination organic frameworks (MOFs) are generated by the assembly of metal coordination centers and organic linkers. Compared to MOFs, porous hydrogen-bonded organic frameworks (HOFs) are ...
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In the title compound, C(15)H(15)N(3)Ox3H(2)O, two of the three water molecules exhibit disorder. The molecular components are linked into a three-dimensional framework by a combination of N-H...O, O-H...N and O-H...O hydrogen bonds.
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Alessandro Stroppa,1,* Domenico Di Sante,2 Sachio Horiuchi,3,4 Yoshinori Tokura,5,6 David Vanderbilt,7 and Silvia Picozzi1 1CNR-SPIN, L’Aquila, Italy 2University of L’Aquila, Physics Department, Via Vetoio, L’Aquila, Italy 3National Institute of Advanced Industrial Science and Technology (AIST) Tsukuba, Ibaraki 305-8562, Japan 4CREST, JST, Tsukuba 305-8562, Japan 5Department of Applied Physics,...
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ژورنال
عنوان ژورنال: Chemical Communications
سال: 2019
ISSN: 1359-7345,1364-548X
DOI: 10.1039/c9cc06707h